This paper presents the experimental results of utilizing a flexible thin-film membrane as a passivebarrier to radon gas diffusion. Nine commercially available membranes of various compositions andthicknesses were evaluated as retardant to radon gas diffusion. The radon gas concentration ratiosacross the thin-film membranes alone and in combination with an adjacent concrete sample (effectivediffusion coefficient) were measured in a laboratory system with state-of-the-art instrumentation.