This paper presents and evaluates a new method, based upon tracer gas techniques, for determining interzonal airflows and effective volumes in a multizone enclosure. Presently used tracer gas techniques have a number of drawbacks including the need for multiple tracers when analyzing a multizone structure. Also, traditional techniques cannot be used to independently determine flows and volumes in the multizone case. The method described in this paper eliminates some of the problems introduced by multiple tracers and allows the independent determination of both flows and volumes.