This paper aims to report the solar and thermal data for various common and innovative materialsused in outdoor urban applications. The tested materials include various types of coatings, tiles andasphalt pavement. In the framework of this research, the spectral reflectance and the emissivity of thematerials were measured using a UV/VIS/NIR spectrophotometer fitted with an integrating sphere andan emissometer. The solar reflectance of the samples was calculated.